22" on a W463 with larger center bore . . .

Nope, you'll need spigot rings, or your G will be undriveable,  what car has 5x130  with 108 bore?

​Gordon

Are you sure they're 5x130 because that's a new one on me, I've checked and I can't find any ford wheels that pcd. A lot of fords are 5x108 pcd

​dont buy them unless your sure. Also 22" rims will give you a crap ride, no off-roading .... Not even driving up kerbs,  and they are very prone to cracking.  I've had some very upset rangerover owners with knackered wheels and no solution

gordon

In the case of a wheel the bolts are there to provide the 'clamp' force, the centre bore 'collar' ensures correct alignment.

In general bolts are never considered a means to align significant rotating masses. That's because:

#1 It isn't accurate enough (small degrees of run-out lead to a very unbalanced mass on something as big as a wheel) and

#2 they aren't designed with sheer forces in mind (perpendicular to their axis).

Although wheel bolts attempt to overcome that with the conical shape of the head, its not something I'd rely on. If you really must use these wheels then you could have a machine shop turn a set of spacing rings , fit those over the collar and then the wheels to those (for reasons not relating to wheel alignment I'm doing exactly that for another G project)

On a slightly related topic its just worth saying that most wheel bolts are only 8.8 rated steel which is why its very important to always use a torque wrench to tighten them correctly for the correct amount of preload (which is whay stops them coming undone.. the mistake that people often make is in assuming that 'tighter is better' - its not, by doing so you stretch the bolt (bad) or hub thread (potentially worse) and although they might stay done up that time you've permanently weakened the fastener and would not want to re-use it again.